Default Applications Configuration
Using System Settings
In the System Settings screen, go to Personalization > Applications > Default Applications, then use the menus to select your preferred default applications.

Using Dolphin
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Open Dolphin.
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Navigate to the folder that contains the file you want to open.
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Right-click the file.
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Go to Open With > Other Application.
The Choose Application dialog appears.
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Choose the application you want to use from the list.
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Select Remember application association for all files of type [file type].
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Click OK.